Introduction
Ionic air purifiers hold the promise of clean air, purified of all known harmful contaminants that threaten our health. These harmful contaminants are not visible to our naked eyes. The weapons against such are very likely to be invisible to our eyes as well. Intuitively, the logic is compelling. Unfortunately, there is no simple solution as google throws up an avalanche of controversy within seconds. Even though I am tempted to quickly get an ionic air purifier to clean the air I breathe, it is clear that more time and effort is needed. Effectiveness is important but safety is paramount in the criteria for selecting an ionic air purifier.
The recent China melamine saga that killed infants also is a timely reminder to us that in buying into any technology or any product, all claims by manufacturers and distributors must be screened to the fullest extent that our resources permit. Where the reactive agent is invisible, it becomes even more critical to focus on it. Invisible ions produced by ionic air purifiers are clearly in this category.
In this article, I am laying out the roadmap as I look into the existing ionic air purifier technologies in the global marketplace. My back-to-basics approach is an attempt, as a layperson, to understand the science behind the technology. A dominant current trend appears to be the creation of an invisible but potent defence shield against airborne molecular contaminants. The dominant global health threat under the scrutiny of scientists is the avian flu virus.
Types of Ionic Air Purifier Technologies
Broadly speaking, air purification technologies can be deployed in either passive or active modes. Passive typically means that impure air is drawn into the air purifier for the reactive agents to work on before re-emerging as cleaned air into the environment. In active mode, the reactive agents are pushed into the environment with the impure air. Combinations of both passive and active modes are often found in many types of ionic air purifiers.
In the global market today, ionic air purifier technologies include the following categories:
(A) Ion generator - positive and negative ions
(B) Ion generator - negative ions only
(C) Photocatalytic Oxidation (POC)
(D) Electrostatic filter
(E) Combos
Ion Generator - Positive and Negative Ions
This combination of positive and negative ions appears to show the most promise for the future of ionic air purifier technology. They have been named as plasmacluster ions by Sharp Corporation, the Japanese corporate powerhouse that invented them.
Plasmaclusters of positive and negative ions encircle and latch onto harmful bacteria and viruses in a deadly grip. In so doing, the production of hydroxyl is activated. Known as nature’s detergent, hydroxyl is a powerful reactive species that plucks out hydrogen molecules from the organic structure of these airborne particulates, thereby killing them. This chemical reaction generates harmless by-products, the main of which is water.
This technology uses a differential ion generator, comprising a positive and a negative ion generator which can be powered in alternate cycles to control the type of ions generated.
Advocates of the positive and negative ions combination claim that a balance of both these ion types is to be found in places like waterfalls and pristine forests, i.e. this is the actual state in nature. Proponents of negative ions believe that negative ions dominate the environment in these natural habitats and even insist that positive ions are harmful. As I progress with my research, I shall be looking for independent scientific studies that support either of these two opposing views.
Ion Generator - Negative Ions
The traditional ionic air purifier produces only negative ions. Currently, this technology dominates market share but it is under serious threat from Sharp’s plasmacluster positive and negative ions technology.
It is claimed that nearly all harmful airborne particulates like dust, smoke and bacteria etc have a positive charge. The positive charges are continually attracted to the negative charges of the ions until sheer mass makes them sink to the ground. These impurities are simply removed by vacuuming. Detractors of negative ion technology believe that the “overweight” particulates on the ground are not destroyed and that the mere act of walking on them re-contaminates the air.
It seems that there are several ways to produce negative ions. This is important because different methods produce different by-products, some of which may be harmful. These methods include:
(1) Water method - this employs what is known as the waterfall or Lenard Effect. Water droplets are splashed onto a metal plate where a small electric charge is applied. This splits the water droplets, a process in which large numbers of negative ions are produced. No harmful by-products result from using the water method to produce ions.
(2) Electron radiation method - this is based on a single negative discharge electrode needle. Millions of negatively-charged electrons are produced when a high voltage pulse is applied to the electrode. An advantage of this method is that no ozone is produced. This is due to the application of a “smaller” energy pulse.
(3) Corona discharge method - this is based on a dual electrode model, a sharp metal electrode and a flat electrode. A very high voltage is applied between the two electrodes. This creates a massive movement of electrons between the electrodes and ionises the air in between them. A criticism of this method is the production of harmful by-products like ozone and nitride oxide.
Photocatalytic Oxidation (POC)
This technology is commonly applied in a passive mode. It relies on the production of the powerful reactive agent, hydroxyl.
Germicidal ultraviolet (UV) light is commonly shone on a catalyst (usually titanium oxide) to produce hydroxyl, oxygen and peroxide, all of which are potent oxidising agents that are very effective at destroying the organic structure of micro-organisms and gaseous volatile organic compounds.
Comprehensive defence is the key strength of POC technology. Proponents of this technology claim that POC inactivates ALL categories of indoor pollution, including:
(1) airborne particulates i.e. dust, pet dander, plant pollen, sea salts, tobacco smoke, industrial and car pollution, etc
(2) bioaerosols i.e. infectious biological compounds (e.g. pathogenic bacteria and viruses) or non-contagious and non-infectious (e.g. non-pathogenic bacteria, molds, cell debris)
(3) volatile organic compounds (VOCs) i.e. gaseous chemicals or odours - benzene, styrene, toluene, chloroform, hexane, ethanol, formaldehyde and ethylene all common emissions from everyday products of our modern home.
POC technology has been criticised for relying on hydroxyl which are believed to attack with equal tenacity the organic structures that make up molecular contaminants and our lung tissue, nose membranes and eye cornea.
Electrostatic Filter
This technology appears to have originated in heavy industries which produced abundant pollutants. In the most common electrostatic filter arrangement, there is a porous dielectric material positioned between two electrodes. A dielectric material does not conduct electricity while metallic electrodes are good conductors that transmit or receive electricity.
Impure air is sucked into the electrostatic purifier and passed over the dielectric material which acts like a sieve. The electrostatic field created between the electrodes causes airborne particulates i.e.dust, smoke contaminants, to stick to the surface of the dielectric. Purified air is pushed out of the purifier and re-circulated.
An ion source is often placed before the electrostatic filter to impart an electric charge to the airborne particulates. Charging the impurities make them adhere more effectively to the dielectric material.
The general criticism of ionisation technology applies to electrostatic filters as well i.e. that harmful ozone is a by-product.
Combo Ionic Air Purifiers
To cater to the various adherents and critics of the diverse technologies, combos incorporate all or some of the above types of technologies. Combos may include:
(1) adsorptive materials such as activated carbon or oxygenated charcoal (known for its extremely porous large surface area) are added to POC technology to enhance the removal of VOCs;
(2) oxidizing catalysts like titanium oxide are coated on various components of all types of air purifiers to enhance VOC elimination;
(3) reducing catalysts such as manganese dioxide are coated near the exit outlets of many air purifiers to reduce reactive species like ozone and nitric oxide which may be harmful;
(4) generating ions by differing methods such as using microwave, UV light, radio frequency waves, and direct current;
(5) tweaking the specifications of any ionic air purifier technology so as to attain the well-known HEPA status without actually using HEPA filters.
Obviously, the process of selecting the most efficient and effective ionic air purifier involves analysing a deluge of information. The safety issues of each technology will need much more investigation. I have also not studied in detail the claims of each technology. It is natural to want to quickly want something that promises to improve the air quality in your homes, offices, factories, schools etc. But I urge you to do your homework and don’t forget to visit me for updates as I continue my search for the ideal ionic air purifier.
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